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Materials Research Lecture

Wednesday, April 6, 2016
4:00pm to 5:00pm
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Spalding Laboratory 106 (Hartley Memorial Seminar Room)
Is Diamond the Best Conductor of Heat?
David Briodo, Professor, Department of Physics, Boston College,

Diamond and its carbon cousins, graphite and graphene, have long been known to be by far the best heat conductors, with room temperature thermal conductivities (k) of over 2000Wm1K1. Other 'high k' materials such as copper and silver have significantly lower values (k=400 Wm1K1). In spite of well-­defined criteria to guide the search for new high k materials, little progress has been made over the years. In this talk, I will describe a new paradigm for achieving high k that we have recently proposed. New criteria are introduced, which stem from fundamental vibrational properties that occur in compounds where the constituent atoms have a large mass ratio. The lattice thermal conductivities of candidate materials have been calculated using a first principles theoretical approach that combines an exact numerical solution of the Boltzmann transport equation for phonons with accurate determination of the harmonic and anharmonic interatomic forces from density functional theory.  Excellent agreement with measured k data has been obtained for a wide range of materials, validating the predictive capability of the theory and contributing insight into the nature of phonon thermal transport in materials. Guided by the new paradigm, we have identified one material, cubic boron arsenide, that should have an exceptionally high room temperature k comparable to the highest known bulk value achieved in diamond. This finding opens opportunities for controlling phonon thermal transport, which may facilitate the design of new high k materials for thermal management applications.


For more information, please contact Jennifer Blankenship by phone at 626-395-3982 or by email at [email protected].