Jonas C. Peters, the Bren Professor of Chemistry, has been appointed director of the Resnick Sustainability Institute. Launched in 2009 with an investment from philanthropists Stewart and Lynda Resnick and located in the Jorgenson Laboratory on the Caltech campus, the Resnick Institute concentrates on transformational breakthroughs that will contribute to the planet's sustainability over the long term.
The Resnick Sustainability Institute, which involves both the Chemistry and Chemical Engineering and Engineering and Applied Science divisions, serves as a prime example of the multidisciplinary approach prized by Caltech.
"Some of the most important challenges in sustainability are also among the most complex," says Peters, who has been a member of the Caltech faculty since 1999. "We are committed to working on problems that are uniquely suited to the Caltech environment. This means starting with fundamentals and leveraging the cross-catalysis of ideas and creativity of this campus to come up with ways to have substantial impact."
Because the world's natural resources are dwindling, Peters wants to continue focusing the Resnick Institute's efforts on efficient energy generation, storage, and use. Some current projects include development of advanced photovoltaics, photoelectrochemical solar fuels and cellulosic biofuels; energy conversion work on batteries and fuel cells; and efficiency in industrial catalysis and advanced research on electrical grid control and distribution.
In addition, the Resnick Institute is exploring new opportunities in the area of water sustainability. In September, the institute hosted a workshop entitled "Water Resilience and Sustainability: Can We Make LA Water Self-Sufficient?" The workshop examined the long-term potential for sustainable water use in urban environments, using the Los Angeles area as a case study.
"The Resnick Sustainability Institute is continuing to build one of the great centers for sustainability research," says Peters. "We are doing this by supporting the most talented young scientists and engineers committed to tackling the fascinating, critical, and yet very difficult challenges of this field."
Arthur B. McDonald (PhD '70), director of the Sudbury Neutrino Observatory (SNO) in Ontario, Canada, and Takaaki Kajita, at the University of Tokyo, Kashiwa, Japan, have shared the 2015 Nobel Prize in Physics for the discovery that neutrinos can change their identities as they travel through space.
McDonald and Kajita lead two large research teams whose work has upended the standard model of particle physics and settled a debate that has raged since 1930, when the neutrino's existence was first proposed by physicist Wolfgang Pauli. Pauli initially devised the neutrino as a bookkeeping device—one to carry away surplus energy from nuclear reactions in stars and from radioactive decay processes on Earth. In order to make the math work, he gave it no charge, almost no mass, and only the weakest of interactions with ordinary matter. Billions of them are coursing through our bodies every second, and we are entirely unaware of them.
There are three types of neutrinos—electron, muon, and tau—and they were, for many years, assumed to be massless and immutable. The technology to detect electron neutrinos emerged in the 1950s, and it slowly became apparent that as few as one-third of the neutrinos the theorists said the sun should be emitting were actually being observed. Various theories were proposed to explain the deficit, including the possibility that the detectable electron neutrinos were somehow transmuting into their undetectable kin en route to Earth.
Solving the mystery of the missing neutrinos would require extremely large detectors in order to catch enough of the elusive particles to get accurate statistics. Such sensitive detectors also require enormous amounts of shielding to avoid false readings.
The University of Tokyo's Super-Kamiokande neutrino detector, which came online in 1996, was built 1,000 meters underground in a zinc mine. Its detector, which counts muon neutrinos and records their direction of travel, found fewer cosmic-ray neutrinos coming up through the Earth than from any other direction. Since they should not be affected in any way by traveling through the 12,742-kilometer diameter of our planet, Kajita and his colleagues concluded that the extra distance had given them a little extra time to change their identities.
McDonald's SNO, built 2,100 meters deep in a nickel mine, began taking data in 1999. It has two counting systems. One is exclusively sensitive to electron neutrinos, which are the type emitted by the sun; the other records all neutrinos but does not identify their types. The SNO also recorded only about one-third of the predicted number of solar electron-type neutrinos—but the aggregate of all three types measured by the other counting systems matched the theory.
The conclusion, for which McDonald and Kajita were awarded the Nobel Prize, was that neutrinos must have a nonzero mass. Quantum mechanics treats particles as waves, and the potentially differing masses associated with muons and taus gives them different wavelengths. The probability waves of the three particle types are aligned when the particle is formed, but as they propagate they get out of synch. Therefore, there is a one-third chance of seeing any particular neutrino in its electron form. Because these particles have this nonzero mass, their gravitational effects on the large-scale behavior of the universe must be taken into account—a profound implication for cosmology.
McDonald came to Caltech in 1965 to pursue a PhD in physics in the Kellogg Radiation Laboratory under the mentorship of the late Charles A. Barnes, professor of physics, emeritus, who passed away in August 2015. "Charlie Barnes was a great mentor who was very proud of his students," says Bradley W. Filippone, professor of physics and a postdoctoral researcher under Barnes. "It is a shame that Charlie didn't get to see Art receive this tremendous honor."
A native of Sydney, Canada, McDonald received his bachelor of science and master's degrees, both in physics, from Dalhousie University in Halifax, Nova Scotia, in 1964 and 1965, respectively. After receiving his doctorate, he worked for the Chalk River Laboratories in Ontario until 1982, when he became a professor of physics at Princeton University. He left Princeton in 1989 and became a professor at Queen's University in Kingston, Canada; the same year, he became the director of the SNO. In 2006, he became the holder of the Gordon and Patricia Gray Chair in Particle Astrophysics, a position he held until his retirement in 2013.
Among many other awards and honors, McDonald is a fellow of the American Physical Society, the Royal Society of Canada, and of Great Britain's Royal Society. He is the recipient of the Killam Prize in the Natural Sciences; the Henry Marshall Tory Medal from the Royal Society of Canada, its highest award for scientific achievement; and the European Physics Society HEP Division Giuseppe and Vanna Cocconi Prize for Particle Astrophysics.
To date, 34 Caltech alumni and faculty have won a total of 35 Nobel Prizes. Last year, alumnus Eric Betzig (BS '83) received the Nobel Prize in Chemistry.
Before embarking on a transcontinental journey, jet airplanes fill up with tens of thousands of gallons of fuel. In the event of a crash, such large quantities of fuel increase the severity of an explosion upon impact. Researchers at Caltech and JPL have discovered a polymeric fuel additive that can reduce the intensity of postimpact explosions that occur during accidents and terrorist acts. Furthermore, preliminary results show that the additive can provide this benefit without adversely affecting fuel performance.
The work is published in the October 2 issue of the journal Science.
Jet engines compress air and combine it with a fine spray of jet fuel. Ignition of the mixture of air and jet fuel by an electric spark triggers a controlled explosion that thrusts the plane forward. Jet airplanes are powered by thousands of these tiny explosions. However, the process that distributes the spray of fuel for ignition—known as misting—also causes fuel to rapidly disperse and easily catch fire in the event of an impact.
The additive, created in the laboratory of Julia Kornfield (BS '83), professor of chemical engineering, is a type of polymer—a long molecule made up of many repeating subunits—capped at each end by units that act like Velcro. The individual polymers spontaneously link into ultralong chains called "megasupramolecules."
Megasupramolecules, Kornfield says, have an unprecedented combination of properties that allows them to control fuel misting, improve the flow of fuel through pipelines, and reduce soot formation. Megasupramolecules inhibit misting under crash conditions and permit misting during fuel injection in the engine.
Other polymers have shown these benefits, but have deficiencies that limit their usefulness. For example, ultralong polymers tend to break irreversibly when passing through pumps, pipelines, and filters. As a result, they lose their useful properties. This is not an issue with megasupramolecules, however. Although supramolecules also detach into smaller parts as they pass through a pump, the process is reversible. The Velcro-like units at the ends of the individual chains simply reconnect when they meet, effectively "healing" the megasupramolecules.
High-speed video showing untreated jet fuel (upper half) and jet fuel treated with 0.3% Caltech polymer (lower half) after a 140 mph projectile impact disperses fuel mist over continuously burning propane torches. The fireball formed by jet fuel is absent for fuel treated with Caltech polymer. Credit: Caltech/JPL
When added to fuel, megasupramolecules dramatically affect the flow behavior even when the polymer concentration is too low to influence other properties of the liquid. For example, the additive does not change the energy content, surface tension, or density of the fuel. In addition, the power and efficiency of engines that use fuel with the additive is unchanged—at least in the diesel engines that have been tested so far.
When an impact occurs, the supramolecules spring into action. The supramolecules spend most of their time coiled up in a compact conformation. When there is a sudden elongation of the fluid, however, the polymer molecules stretch out and resist further elongation. This stretching allows them to inhibit the breakup of droplets under impact conditions—thus reducing the size of explosions—as well as to reduce turbulence in pipelines.
"The idea of megasupramolecules grew out of ultralong polymers," says research scientist and co–first author Ming-Hsin "Jeremy" Wei (PhD '14). "In the late 1970s and early 1980s, polymer scientists were very enthusiastic about adding ultralong polymers to fuel in order to make postimpact explosions of aircrafts less intense." The concept was tested in a full-scale crash test of an airplane in 1984. The plane was briefly engulfed in a fireball, generating negative headlines and causing ultralong polymers to quickly fall out of favor, Wei says.
In 2002, Virendra Sarohia (PhD '75) at JPL sought to revive research on mist control in hopes of preventing another attack like that of 9-11. "He reached out to me and convinced me to design a new polymer for mist control of jet fuel," says Kornfield, the corresponding author on the new paper. The first breakthrough came in 2006 with the theoretical prediction of megasupramolecules by Ameri David (PhD '08), then a graduate student in her lab. David designed individual chains that are small enough to eliminate prior problems and that dynamically associate together into megasupramolecules, even at low concentrations. He suggested that these assemblies might provide the benefits of ultralong polymers, with the new feature that they could pass through pumps and filters unharmed.
When Wei joined the project in 2007, he set out to create these theoretical molecules. Producing polymers of the desired length with sufficiently strong "molecular Velcro" on both ends proved to be a challenge. With the help of a catalyst developed by Robert Grubbs, the Victor and Elizabeth Atkins Professor of Chemistry and winner of the 2005 Nobel Prize in Chemistry, Wei developed a method to precisely control the structure of the molecular Velcro and put it in the right place on the polymer chains.
Integration of science and engineering was the key to success. Simon Jones, an industrial chemist now at JPL, helped Wei develop practical methods to produce longer and longer chains with the Velcro-like end groups. Co–first author and Caltech graduate student Boyu Li helped Wei explore the physics behind the exciting behavior of these new polymers. Joel Schmitigal, a scientist at the U.S. Army Tank Automotive Research Development and Engineering Center (TARDEC) in Warren, Michigan, performed essential tests that put the polymer on the path toward approval as a new fuel additive.
"Looking to the future, if you want to use this additive in thousands of gallons of jet fuel, diesel, or oil, you need a process to mass-produce it," Wei says. "That is why my goal is to develop a reactor that will continuously produce the polymer—and I plan to achieve it less than a year from now."
"Above all," Kornfield says, "we hope these new polymers will save lives and minimize burns that result from postimpact fuel fires."
These gifts are the latest in a decades-long association between the foundation and Caltech that has advanced research and education in fields including sustainable energy, materials science, and applied physics.
"The industrial-academic partnership between Dow and Caltech exemplifies our two institutions' commitment to addressing urgent problems that confront the world," says Thomas F. Rosenbaum, Caltech's president, holder of the Sonja and William Davidow Presidential Chair, and professor of physics. "We are grateful to The Dow Chemical Company Foundation for enabling chemists and chemical engineers to pursue their best ideas in defining areas such as materials chemistry and renewable energy."
One grant will underwrite start-up costs for new faculty members, giving CCE a key advantage in attracting creative, original thinkers. This is especially important funding for CCE—an academic program that has pushed the frontiers of discovery and trained generations of scientific leaders by making every recruitment count. This approach has helped the division build an active faculty that includes three Nobel laureates, four National Medal of Science recipients, one recipient of the National Medal of Technology and Innovation, and 20 members of the National Academies.
The second commitment will help CCE update and maintain equipment shared by all of its scholars—facilities for nuclear magnetic resonance, electron paramagnetic resonance, and mass spectrometry. The funds also will support the cost of teaching graduate students how to use these instruments.
"Dow and Caltech have built a robust relationship, with a history of advancing research that addresses some of society's toughest challenges. These latest grants from the foundation will expand research opportunities, delivering benefits to engineering, the science community, the Institute, and ultimately society," says A.N. Sreeram, Dow's corporate vice president for research and development.
The link between the Institute and Dow stretches back more than 30 years and includes numerous joint research projects as well as steady foundation support for Caltech's Dow Travel Fellowship and Dow's Seminar Series in Organic and Organometallic Chemistry.
In 2009, Dow and Caltech initiated a $4.2 million partnership that fueled investigations aimed at creating solar cells from inexpensive, abundant materials. That same year, Dow's Graduate Fellowship in Chemical Sciences and Engineering was endowed with help from the Gordon and Betty Moore Matching Program.
A $10 million collaboration followed in 2011, providing resources for the Resnick Sustainability Institute at Caltech as well as endowing five graduate fellowships in chemistry and chemical engineering and another five fellowships in energy science. The agreement made Dow a member of Caltech's Corporate Partners Program, which provides a gateway for exchange and productive collaborations between industry and the Institute.
"Caltech's leadership in science education and sustainability research make these grants a perfect fit in advancing innovation and building the workforce of tomorrow," says Rob Vallentine, president and executive director of The Dow Chemical Company Foundation and global director of corporate citizenship at The Dow Chemical Company. "We are pleased to provide resources that enable Caltech faculty and students to advance science and invent important technologies."
Established in 1979, The Dow Chemical Company Foundation contributes to sustainable communities by supporting strategic philanthropic investments to build the workforce of tomorrow and drive innovative global solutions to address the world's most pressing challenges. The foundation is a separately governed private foundation designed to carry out the charitable efforts of Dow.
Caltech undergraduate students returned to campus this week, many after spending the summer working at companies in biotechnology, technology, and finance, among other fields. These students have had the opportunity to learn firsthand about the career opportunities and paths that may be available to them after graduation. They also had the chance to put Caltech's rigorous academic and problem-solving training to the test.
In the summer of 2015, nearly a third of returning sophomores, juniors, and seniors were placed in an internship position through Caltech's Summer Undergraduate Internship Program (SUIP). The program, run through the Institute's Career Development Center (CDC), helps connect current undergraduate students with a wide range of companies and businesses that can provide practical skills and work experiences that give the students an edge in the future job market.
Many undergraduates find paid summer internships through the CDC, says Lauren Stolper, the director of fellowships, advising, study abroad, and the CDC. The center organizes fall and winter career fairs and offers workshops related to finding internships; provides individual advising on internship options and conducting a job hunt for an internship; organizes interviews for students through its on-campus recruiting program; and provides web-based internship listings and company information through Techerlink, its online job-posting system.
Through the formal establishment of SUIP two years ago—thanks, in part, to the initiative of Craig SanPietro (BS '68, engineering; MS '69, mechanical engineering) and with seed money provided by him and three of his alumni friends and former Dabney House roommates, Peter Cross (BS '68, engineering), Eric Garen (BS '68, engineering), and Charles Zeller (BS '68, engineering)—the CDC has been able to dedicate even more time and attention to helping undergraduates secure these important positions, Stolper says.
"Through internships, students have the opportunity to learn more about the practical applications of their knowledge by contributing to ongoing projects under the guidance of professionals," says Aneesha Akram, a career counselor for internship development/advising, who oversees SUIP.
"Completing summer internships help undergraduates become competitive candidates for full-time positions," says Akram. "When it comes to recruiting for full-time positions, companies seek out candidates with previous internship experience. We have found that many large companies extend return offers and full-time conversions to students who previously interned with them."
The infographic at the above right provides a snapshot of Caltech undergraduate internships over this past summer. Students seeking internships for next summer can contact Akram or look at the CDC website for more information.